(1,5-Diphenylthiocarbazonato-κS)trimethyltin(IV)
نویسندگان
چکیده
In the title compound, [Sn(C13H11N4S)(CH3)3], the Sn(IV) atom is coordinated by an S atom from the 1,5-diphenyl-thio-carbazonato (L) ligand [Sn-S 2.4710 (6) Å] and by three methyl groups [Sn-C 2.123 (3)-2.130 (2) Å] in a distorted tetra-hedral geometry. The aromatic rings of the L ligand form a dihedral angle of 2.1 (1)°.
منابع مشابه
catena-Poly[[trimethyltin(IV)]-μ-5-methylthiophene-2-carboxylato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-quinaldato]
The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.
متن کاملcatena-Poly[[aquatrimethyltin(IV)]-{[trimethyltin(IV)]-μ3-thiophene-2,5-dicarboxylato}]
In the title compound, [Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O)](n), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H⋯O hydrogen bonding.
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-phenylseleninato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-1,2,3-benzotriazol-1-ido-κ2 N 1:N 3]
In the title coordination polymer, [Sn(CH(3))(3)(C(6)H(4)N(3))](n), the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with the methyl groups in equatorial positions and two N atoms of two symmetry-related benzotriazolide anions in axial positions. The anion bridges adjacent metal atoms, forming zigzag polymeric chains parallel to [011] and [0[Formula: see text]1].
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